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inversion. The sphere pore inversion can also be indicated by SEM observation on the transition of some isolated spheres. Moreover, the porous structure can be obtained by simply dropping THF on the colloidal array surface, although the edges of the pores are less regular. The formation of the porous structures is closely related with the amount of THF dropped. SEM observation indicates that when the THF amount is less than the proper amount, some pores just begin to form and some spheres can still be seen. When the THF amount is large, parts of the colloidal sphere array are transformed to a at lm without the porous character (Li et al., 2006c). Although the exact mechanism for the sphere pore inversion is still unclear at the current stage, some basic characteristics of the process can be discussed as

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Figure 5.25. SEM images: (a) array of the ellipsoidal colloids, (b) the porous lm with elliptical pores. Source: From Li et al., 2006c.

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follows. The colloidal spheres possess the core-shell structure with a hydrophobic core and a hydrophilic corona. When the colloids are exposed to the THF atmosphere for some time period, the hydrophobic core can be swollen and the colloidal arrays gradually transform to an inhomogeneous thin lm. When the lm is further interacted with THF, the inhomogeneous lm can convert into the porous structures. In the process, the parts with poorer solubility in THF will shrink and the polymeric chains are rearranged to decrease the contact area between these parts and THF. The high regularity of the nal structure seems to indicate that this process is a highly coordinated process. When the hydrophobic fraction further moves out of the original core regions of the colloidal array, it will not only release the tension caused by chain collapse during the colloid formation but will also minimize the surface tension by forming an interfacial layer between the solvent and the hydrophilic segments. The perfect circular shape of the pores could be an evidence of the process to minimize the surface tension. With the shrinkage of the hydrophilic parts at the same time, the intermediate structure can nally transform to the ordered porous lm.

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The preceding investigation results demonstrate that the polydispersed amphiphilic azo polymers can be used to construct various well-organized structures through self-assembling processes at different levels. The azo polymers can form uniform colloidal spheres, 2-D arrays of colloidal spheres, and porous lms based on different self-assembling processes. Novel photoresponsive properties have been observed for the colloids and colloidal arrays, which include photoinduced elongation of colloids, photoinduced separation of two components from hybrid colloids, and photoinduced dichroism of the colloid array. These observations can give some new insights into the self-assembly nature and photoresponsive properties concerning azo polymers. Some new potential applications can be expected on the basis of the understandings.

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Archut A, Azzellini GC, Balzani V, Cola LD, Vogtle F. 1998. Toward photoswitchable dendritic hosts: interation between azobenzene functionalized dendrimers and eosin. J Am Chem Soc 120:12187 12191. Astrand PO, Ramanujam PS, Hvilsted S, Bak KL, Sauer SPA. 2000. Ab initio calculation of the electronic spectrum of azobenzene dyes and its impact on the design of optical data storage materials. J Am Chem Soc 122:3482 3487. Balsara NP, Tirrell M, Lodge TP. 1991. Micelle formation of BAB triblock copolymers in solvents that preferentially dissolve the A block. Macromolecules 24:1975 1986.

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